4.8 Article

Titanocene-catalyzed regioselective syn-hydrosilation of alkynes

Journal

ORGANIC LETTERS
Volume 5, Issue 19, Pages 3479-3481

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol035277t

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[GRAPHICS] The titanium catalyst, which was generated in situ from titanocene dichloride and 2 equiv of butyllithium, was found to catalyze hydrosilation of a variety of alkynes with excellent regio- and syn-selectivity.

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