Journal
ORGANIC LETTERS
Volume 5, Issue 19, Pages 3491-3494Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035322x
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- NIGMS NIH HHS [GM54161] Funding Source: Medline
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[GRAPHICS] An approach to the highly functionalized tricyclic core of guanacastepene A has been developed using a rhodium(I)-catalyzed allenic Pauson-Khand reaction, This approach constitutes a conceptually novel strategy for the synthesis of this tricyclic framework, whereby the six-membered ring is formed intially followed by simultaneous formation of the five- and seven-membered rings.
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