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Highly enantioselective hydrogenation of enamides catalyzed by rhodium-monodentate phosphoramidite complex derived from H8-BINOL

TETRAHEDRON-ASYMMETRY (2003)

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Journal

TETRAHEDRON-ASYMMETRY
Volume 14, Issue 18, Pages 2687-2691

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2003.07.005

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Categories

Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical

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A series of monodentate phosphoramidite ligands derived from H-8-BINOL have been synthesized. The ligands are used in the Rh-catalyzed asymmetric hydrogenation of enamides to give the acetamides in up to 99% ee. (C) 2003 Elsevier Ltd. All rights reserved.

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