4.7 Article

Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells-Dawson structure, α-[Si2W18O66]16-

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 18, Pages 2360-2361

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b307276b

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Acidification of K(10)A-alpha-[SiW9O34] in aqueous solution leads to the formation of alpha-[Si2W18O66](16-), built up from two A-alpha-{SiW9O34} subunits, which reacts with metal cations to form potassium and mixed potassium-transition metal complexes.

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