Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 107, Issue 38, Pages 10321-10324Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp034537l
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The resonance wavelength of the surface plasmon in gold nanoparticles above a gold substrate has been measured using transmission absorption spectroscopy. Gold nanoparticles with diameters in the range of 20-100 nm are immobilized onto a thin gold film deposited onto a glass substrate by a self-assembled monolayer of aminoethanethiol. The resonance wavelength obtained in the experiments shows a large red shift. Its dependence on the particle diameter shows good agreement with theoretical results that are calculated using a static approximation that includes multipole effects.
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