Journal
SYNLETT
Volume -, Issue 12, Pages 1883-1885Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2003-41474
Keywords
aerobic conditions; allylation; asymmetric catalysis; rhodium; pincer complex
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A simple and general protocol is described for the enantioselective addition of methallyltributyltin to aldehydes catalyzed by chiral (Phebox)RhCl2(H2O) complexes 1 [Phebox = 2,6-bis(oxazolinyl)phenyl]. The reaction can be performed even under aerobic conditions to afford the corresponding optically active homoallylic alcohols in good yields with high enantioselectivities (90-99% ee).
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