Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 6, Issue 10, Pages 1332-1334Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2003.06.002
Keywords
coordination polymer; one-dimensional structure; hydrothermal reaction; helical chain; binuclear copper; 2,2 '-biphenyldicarboxylate
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The first I-D double-helical-chain coordination polymer, [(H(2)O)Cu(BPDC)] (2,2'-biphenyldicarboxylate), based upon the binuclear square pyramidal copper(II)-pair motifs has been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction technique. [(H(2)O)Cu(BPDC)] crystallized in orthorhombic crystal system, space group Cmca with unit cell dimensions a = 21.073(6) Angstrom, b = 7.118(2) Angstrom and c = 17.670(5) Angstrom, Z = 8. (C) 2003 Elsevier B.V. All rights reserved.
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