Journal
SOLID STATE COMMUNICATIONS
Volume 128, Issue 2-3, Pages 79-84Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0038-1098(03)00618-5
Keywords
spin-chain oxides; spin-glass; magnetic ordering
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The results of ac and dc magnetization and heat capacity measurements on the oxides, Ca3Co1+xMn1-xO6, forming in a K4CdCl6-derived rhombohedral quasi-one-dimensional crystal structure, are reported. As far as Ca3Co2O6 is concerned, the results reveal a truly complex nature of the two magnetic transitions, identified to set in at 24 and 12 K in the previous literature. However, partial replacement of Co by Mn apparently results in a long magnetic ordering of an anti ferromagnetic type (below 13 and 18 K for x = 0.0 and 0.25, respectively), instead of spin-glass freezing in spite of the fact that there is Co-Mn disorder; in addition, interestingly there are hysteretic spin reorientation effects as revealed by the isothermal magnetization behavior. (C) 2003 Elsevier Ltd. All rights reserved.
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