Journal
PURE AND APPLIED CHEMISTRY
Volume 75, Issue 10, Pages 1443-1451Publisher
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/pac200375101443
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The unique availability of substituted cyclohexa-1,4- and 1,3-dienes, notably enol ethers, from Birch reduction of anisoles, permits many novel synthetic reactions of general utility. The total synthesis of several natural products derived from polyketides have been accomplished using a Diels-Alder and Alder-Rickert process. The strategies of the synthesis are discussed.
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