Journal
COORDINATION CHEMISTRY REVIEWS
Volume 245, Issue 1-2, Pages 17-29Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(03)00030-4
Keywords
cxobalt(II) complexes; pyridazine; triazole; triazolate; magnetochemistry
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Structurally characterised cobalt(II) complexes containing pyridazine, triazole or triazolate ligands are the subject of this review. Firstly a brief introduction to Schiff-base macrocyclic chemistry is given and then the crystal structures and magnetic properties of pyridazine-containing cobalt(II) complexes are discussed, focussing on macrocyclic complexes. There follows a discussion of the crystal structures, as well as the magnetic behaviour where known, of cobalt(II) complexes containing the triazole moiety in a N-1,N-2-bridging fashion. Finally an overview of reported complexes where the triazole unit has been incorporated into a Schiff-base macrocyclic framework is provided. None of these triazole-containing macrocyclic complexes has been structurally characterised. (C) 2003 Elsevier B.V. All rights reserved.
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