Journal
JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume 33, Issue 10, Pages 933-937Publisher
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1025881213041
Keywords
electrocatalysis; epoxidation; hydrogen peroxide; silicalite; trickle-bed electrode
Categories
Ask authors/readers for more resources
The epoxidation of allyl alcohol with in situ generated hydrogen peroxide was performed in an electrochemical cell with a trickle-bed electrode, composed of carbon black, graphite, PTFE and titanium silicalite-1 (TS-1) as heterogeneous epoxidation catalyst. Mass transport in interaction with the catalytic activity limits the epoxidation rate. The conversion of allyl alcohol increases with increase in the content of epoxidation catalyst in the electrode. In contrast, the specific reaction rate decreases due to the reduced accessibility of active sites in the catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available