Journal
ORGANIC LETTERS
Volume 5, Issue 20, Pages 3555-3558Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0349920
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The enantioselective borodeuteride reduction catalyzed by optically active beta-ketolminato cobalt complexes was applied to N-(di(o-tolyl)phosphinyl)-aldimines to afford the corresponding optically active deuterated primary amines in high yields with high enantiomeric excesses after simple deprotection. The present deuteride reduction of aldimines is in the opposite sense of the enantioselective for the previously reported borohydride reduction of ketones or diphenylphosphinyl aldimines. The stereochemical course in these enantioselective reductions is discussed.
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