Journal
ORGANIC LETTERS
Volume 5, Issue 21, Pages 3839-3842Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol030088w
Keywords
-
Categories
Ask authors/readers for more resources
[GRAPHICS] The enantioselective total syntheses of (+)-azimine and (+)-carpaine have been developed, starting with (S)-1,2,4-butanetriol as a single source of chirality. The key common feature in these syntheses involves stereoselective intramolecular hetero-Diels-Alder reaction of an acylnitroso compound. The critical macrocyclic dilactonization of the N-Cbz derivatives of azimic acid and carpamic acid was efficiently achieved by using the Yamguchi macrocyclization conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available