Journal
ORGANIC LETTERS
Volume 5, Issue 21, Pages 3851-3853Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035377z
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[GRAPHICS] N-Carbamoylmethyl-N'-tosyl guanidine 2 reacts easily with primary alkylamines to afford substituted carboxamides 3. The reaction proceeds via a five-membered-ring intermediate 5, which could be isolated, and features a rare example of an intermolecular transamidation reaction under mild conditions.
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