Journal
INORGANIC CHEMISTRY
Volume 42, Issue 21, Pages 6923-6928Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic020705x
Keywords
-
Categories
Ask authors/readers for more resources
Aqueous solutions of potassium ferrate(VI) cleanly and rapidly oxidize hydroxylamine to nitrous oxide, N-methylhydroxylamine to nitrosomethane, N-phenylhydroxylamine to nitrosobenzene, and O-methylhydroxylamine to methanol and nitrogen. The kinetics show first-order behavior with respect to each reactant and a two term component representing acid dependent and independent pathways. A general mechanism involving intermediate formation coupled with a two-electron oxidation is proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available