4.7 Article

The kinetics and mechanism of the ferrate(VI) oxidation of hydroxylamines

Journal

INORGANIC CHEMISTRY
Volume 42, Issue 21, Pages 6923-6928

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic020705x

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Aqueous solutions of potassium ferrate(VI) cleanly and rapidly oxidize hydroxylamine to nitrous oxide, N-methylhydroxylamine to nitrosomethane, N-phenylhydroxylamine to nitrosobenzene, and O-methylhydroxylamine to methanol and nitrogen. The kinetics show first-order behavior with respect to each reactant and a two term component representing acid dependent and independent pathways. A general mechanism involving intermediate formation coupled with a two-electron oxidation is proposed.

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