Journal
ORGANOMETALLICS
Volume 22, Issue 22, Pages 4361-4363Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om030363i
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The iron carbene cation [Fe(CO)(2)(eta(5)-C5H5)-{=CMe(OMe)}](+) reacts with reductively activated [Mn(CO)(3)(eta(4)-C6H6)](-) to form the carbene/benzene adduct [Mn(CO)(3){eta(5)-C6H6-CMe(OMe)Fe(CO)(2)(eta(5)-C5H5)}] (3). Reduction of 3 is proposed to give species in which there are ferrocyclic benzene-derived ligands.
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