Journal
TETRAHEDRON
Volume 59, Issue 44, Pages 8821-8825Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2003.08.067
Keywords
2-oxo-2-vinyl 1,3,2-dioxaphospholanes; 2-oxo-2-vinyl 1,3,2-dioxaphosphorinanes; palladium; vinyl bromide; transesterification; DFT calculations
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The title compounds are prepared via a two step procedure involving a transesterification between a diol and diethyl phosphite followed by a palladium-catalyzed coupling of the so-obtained cyclic phosphite with vinyl bromide. Theoretical DFT calculations have been performed on phosphonate and phosphite anions models in order to estimate stereoelectronic effects in five-membered and six-membered ring compounds. (C) 2003 Elsevier Ltd. All rights reserved.
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