Journal
CHEMICAL PHYSICS LETTERS
Volume 380, Issue 5-6, Pages 620-623Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2003.08.096
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Boron nitride (BN) nanocage clusters of B24N24 were synthesized and detected by laser desorption time-of-flight mass spectrometry. The B24N24 clusters consisted of 4-, 6- and 8-membered BN rings satisfying the isolated tetragonal rule, which was optimized by molecular orbital calculations. The electronic structure showed a bandgap energy of 4.9 eV, which is smaller than that of B36N36 cluster. (C) 2003 Elsevier B.V. All rights reserved.
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