3.9 Article

X-ray structure of {[μ-N,N′-Bis(salicylidene)-1,3-propane-diamine](dimethylformamide) zinc(II)} dibromo cadmium(II)

Journal

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume 33, Issue 11, Pages 825-829

Publisher

KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1027497427264

Keywords

crystal structure; dinuclear zinc and cadmium complex

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The title compound, forms crystals which are the orthorhombic system, space group P2(1)2(1)2(1), with unit cell dimensions a = 10.3928(12) Angstrom, b = 14.6298(13) Angstrom, c = 15.9514(11) Angstrom, V = 2425.3(4) Angstrom(3). The cell contains four molecules. The structure is a heteronuclear dimeric complex with Zn-II and Cd-II ions. The coordination around the Zn-II ion is distorted square-pyramid and the Cd-II ion is distorted tetrahedral coordination. The Zn...Cd distance is 3.3594(7) Angstrom.

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