Journal
TETRAHEDRON LETTERS
Volume 44, Issue 45, Pages 8331-8334Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2003.09.031
Keywords
indium compounds; diazo compounds; C-alkylation; heteroaromatics
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Pyrroles and indoles react smoothly with alpha-diazocarbonyl compounds in the presence of 10 mol%, of InBr3, under mild conditions to afford the corresponding 2- and 3-alkyl pyrrole and 3-alkyl indole derivatives, respectively, in good yields with high selectivity. (C) 2003 Elsevier Ltd. All rights reserved.
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