Journal
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
Volume 26, Issue 1-2, Pages 41-45Publisher
ELSEVIER
DOI: 10.1016/S1381-1177(03)00147-4
Keywords
[bdmim]BF4; enantioselectivity; lipase; recycling; transesterification
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1-Butyl-2,3-dimethylimidazolium tetrafluoroborate ([bdmim]BF4) was found to be an excellent solvent to realize a lipase-recycling system using vinyl acetate as acyl donor. No accumulation of an acetaldehyde oligomer was observed in this solvent system and it was possible to use the lipase repeatedly 10 times while still maintaining perfect enantioselectivity and high reactivity. (C) 2003 Elsevier B.V. All rights reserved.
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