Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 21, Pages 3918-3923Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200300272
Keywords
heterometallic complexes; isocyanide ligands; bridging ligands; isomers; group 6 elements
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The one-pot/three-step solution synthesis of a library of nine directional, dinuclear mixed-metal complexes composed of different metal-carbonyl units (M = Cr, Mo, W) and a bifunctional bridging isocyanide Schiff-base ligand is described. The well-defined metal sequence in these complexes with Cr, Mo, and W in two positions can be determined post-synthesis by a combination of spectroscopic methods. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
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