Journal
ORGANIC LETTERS
Volume 5, Issue 23, Pages 4397-4400Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035681s
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A ligandless and base-free Cu-catalyzed protocol for the cross-coupling of arylboronic acids and potassium aryltrifluoroborate salts with primary and secondary aliphatic amines and anilines is described. The process utilizes catalytic copper(II) acetate monohydrate and 4 Angstrom molecular sieves in dichloromethane at slightly elevated temperatures under an atmosphere of oxygen. A broad range of functional groups are tolerated on both of the cross-coupling partners.
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