Journal
ORGANIC LETTERS
Volume 5, Issue 23, Pages 4505-4507Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol035828f
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The bimetallic titanium complex [(salen)TiO](2), where salen is the ligand derived from (R,R)-cyclohexanediamine and 3,5-di-tert-butyl-salicylaldehyde, has been shown to catalyze the asymmetric addition of ethyl cyanoformate to aldehydes leading to cyanohydrin carbonates with high enantiomeric excesses.
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