Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 41, Issue 22, Pages 3549-3555Publisher
WILEY
DOI: 10.1002/pola.10835
Keywords
alternating copolymerization; polycarbonates; carbon dioxide; epoxide; anionic polymerization; copolymerization
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The first successful example of the formation of polycarbonate from 1-atm carbon dioxide and epoxide was demonstrated by the alternating copolymerization of carbon dioxide and epoxide with manganese porphyrin as a catalyst. The copolymerization of carbon dioxide and cyclohexene oxide with (porphinato)manganese acetate proceeded under the 1-atm pressure of carbon dioxide to give a copolymer with an alternating sequence. (C) 2003 Wiley Periodicals, Inc.
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