Journal
INORGANIC CHEMISTRY
Volume 42, Issue 23, Pages 7348-7350Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic034886u
Keywords
-
Categories
Ask authors/readers for more resources
Iron(II) 2-aza-21-carbaporphyrins have been characterized by paramagnetically shifted H-1 and H-2 NMR spectra. The high-spin iron(II) complex (HCTPPH)(FeBr)-Br-11 displays the beta-H resonances which reflect the combination sigma and pi routes of spin density delocalization. The uniquely large isotropic shift of the inner H(21) hydrogen (812 ppm, 298 K) indicates an Fe-11-{C(21)-H} agostic interaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available