Journal
ORGANIC LETTERS
Volume 5, Issue 24, Pages 4579-4581Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0356340
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N'-Substituted guanidinlocarbonyl pyrroles 7 were synthesized for the first time by activation of a Boc-protected guanidiniocarbonyl pyrrole 3 with triflic anhydride and subsequent reaction with a primary amine. These guanidinium cations are efficient receptors for the complexation of amino acid carboxylates even in water (K-assoc C > 10(3) M-1) as could be shown by UV titration studies.
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