4.8 Article

Mercuric triflate-(TMU)3-catalyzed cyclization of ω-arylalkyne leading to dihydronaphthalenes

Journal

ORGANIC LETTERS
Volume 5, Issue 24, Pages 4563-4565

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol035622e

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Efficient arylyne cyclization catalyzed by the Hg(OTf)(2)-(TMU)(3) complex has been developed. The reaction was carried out at ambient temperature in acetonitrile, and the catalytic cycle reaches up to 1000 turnovers.

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