The structure and sharpness of (Mg,Fe)2SiO4 phase transformations in the transition zone

To calculate accurately the pressure interval and mineral proportions (i.e. yields) across the olivine to wadsleyite and wadsleyite to ringwoodite transformations requires a detailed knowledge of the non-ideality of Fe-Mg mixing in these (Mg,Fe)(2)SiO4 solid solutions. In order to constrain the activity-composition relations that describe non-ideal mixing, Fe-Mg partitioning experiments have been conducted between magnesiowustite and (Mg,Fe)(2)SiO4 olivine, wadsleyite and ringwoodite as a function of pressure at 1400degreesC. Using known activity-composition relations for magnesiowustite the corresponding relations for the three polymorphs were determined from the partitioning data. In all experiments the presence of metallic iron ensured redox conditions compatible with the Earth's transition zone. The non-ideality of the (Mg,Fe)(2)SiO4 solid solutions was found to decrease in the order W-FeMg(wadsleyite) > W-FeMg(ringwoodite) > W-FeMg(olivine). These partitioning data were used, along with published phase equilibria measurements for the Mg2SiO4 and Fe2SiO4 end-member transformations, to produce an internally consistent thermodynamic model for the Mg2SiO4-Fe2SiO4 system at 1400degreesC. Using this model the pressure interval of the olivine to wadsleyite transformation is calculated to be significantly smaller than previous determinations. By combining these results with Fe-Mg partitioning data for garnet, the widths of transition zone phase transformations in a peridotite composition were calculated. The olivine to wadsleyite transformation at 1400degreesC in dry peridotite was found to occur over a pressure interval equivalent to approximately 6 kin depth and the mineral yields were found to vary almost linearly with depth across the transformation. This transformation is likely to be even sharper at higher temperatures or could be significantly broader in wet mantle or in regions with a significant vertical component of mantle flow. The entire range of estimated widths for the 410 kin discontinuity (4-35 km) could, therefore, be explained by the olivine to wadsleyite transformation in a peridotite composition over a range of quite plausible mantle temperatures and H2O contents. The wadsleyite to ringwoodite transformation in peridotite mantle was calculated to take place over an interval of 20 kin at 1400degreesC. This transformation yield was also found to be near linear. (C) 2003 Elsevier B.V. All rights reserved.