Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 687, Issue 2, Pages 229-248Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2003.07.028
Keywords
carbenes; catalysis; CC-coupling; CN-coupling; palladacycles; palladium; phosphines
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Due to the great importance of palladium-catalyzed Heck-type reactions in scientific and industrial chemistry, a lot of publications and reviews have been published during the last years describing this matter under different aspects. This article presents a summary of catalytic applications of palladium complexes with phosphorus ligands containing a metallated sp(3)-carbon centre (palladacycles) or with N-heterocyclic carbene ligands in C-C and C-N coupling reactions of aryl halides including recent results of mechanistic discussions about their role in the catalytic cycle. (C) 2003 Elsevier B.V. All rights reserved.
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