4.4 Article

Synthesis and dielectric study of new liquid-crystalline polysiloxanes presenting a thioether spacer

Journal

MACROMOLECULAR CHEMISTRY AND PHYSICS
Volume 204, Issue 18, Pages 2222-2232

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200300012

Keywords

dielectric properties; liquid-crystalline polymers (LCP); polysiloxanes; structure-property relations

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Three new cyanobiphenyl polysiloxanes presenting long thioether spaces have been carried out. This type of spacer leads to very stable liquid-crystallinity phenomenon. Dielectric analysis results show that the thioether spacer brings much more molecular flexibility to the system.

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