Artificial flux pinning centers in large, single-grain (RE)-Ba-Cu-O superconductors

Second-phase, nanoscale inclusions of composition Y2Ba4CuMOy (M=U, Nb, Ta, W, Mo, and Re), which form artificial pinning centers, have been introduced into large, single-grain [rare-earth (RE)]-Ba-Cu-O superconductors. A significant improvement in critical current density is observed in these samples, due presumably to various combinations of normal conducting, paramagnetic, and geometrical properties of the Y2Ba4CuMOy particles in the superconducting (RE)Ba2Cu3O7-delta (RE-123) phase matrix. These Y2Ba4CuMOy phase particles are chemically stable in the Ba-Cu-O liquid during peritectic solidification, unlike Y2BaCuO5 (Y-211) phase particles in Y-Ba-Cu-O, which opens a processing window for the fabrication of nanostructured large, single-grain (RE)-Ba-Cu-O superconductors with enhanced flux pinning for high-field engineering applications. (C) 2003 American Institute of Physics.