Journal
MACROMOLECULAR BIOSCIENCE
Volume 3, Issue 12, Pages 725-728Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mabi.200300012
Keywords
biodegradation; hydrogel; proteinase K; temperature-responsive
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Novel linear poly(NIPA-co-CL) copolymers have been synthesized by radical copolymerization of N-isopropylacrylamide (NIPA) and 2-methylene-1,3-dioxepane (MDO). The structure of copolymers was confirmed by H-1 NMR and IR spectroscopy. Cross-linked poly(NIPA-co-CL) hydrogels have also been prepared in toluene using N,N'-methylenebisacrylamide as cross-linking agent. The hydrogels thus obtained exhibit good temperature response and are biodegradable in the presence of proteinase K.
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