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Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to enones with new peptidyl phosphane ligands

TETRAHEDRON-ASYMMETRY (2003)

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Journal

TETRAHEDRON-ASYMMETRY
Volume 14, Issue 24, Pages 3823-3826

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2003.10.002

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Categories

Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical

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Copper catalysts based on new peptidyl phosphane ligands have been developed for enantioselective conjugate additions of dialkylzinc reagents to cyclic enones. Enantioselectivities greater than 97% ee have been observed. (C) 2003 Elsevier Ltd. All rights reserved.

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