Journal
CHEMPHYSCHEM
Volume 4, Issue 12, Pages 1283-1289Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.200300854
Keywords
density functional calculations; fluorine; nanotubes; solubility; thermochemistry
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Fluorination of single-walled carbon nanotubes by reaction with elemental fluorine at elevated temperatures provides fluorinated single-walled carbon nonotubes (F-SWNT), which have the highest degree of functionalization (up to F/C= 1/2) of any derivatized carbon-nanotube material reported to dote. Also, F-SWNTs have received more scrutiny than any other functionalized carbon nanotubes. This Minireview covers experimental and computational investigations of F-SWNTs with a focus on the nature and the strength of the C-F linkage.
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