4.4 Article

Palladium-catalyzed phosphination of functionalized aryl triflates

Journal

TETRAHEDRON
Volume 59, Issue 51, Pages 10295-10305

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2003.10.061

Keywords

phosphination; aryl triflates; triphenylphosphine

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Catalytic user-friendly approach to the syntheses of various functionalized aromatic phosphines from their corresponding substituted aryl triflates and triarylphosphines was accomplished. This method is carried out in neutral media and compatible with many functional groups including aldehyde, keto, ester, nitrile, ether and pyridyl groups. (C) 2003 Elsevier Ltd. All fights reserved.

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