Journal
INORGANIC CHEMISTRY
Volume 42, Issue 25, Pages 8250-8254Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic034976z
Keywords
-
Categories
Ask authors/readers for more resources
Ce(NO3)(3).6H(2)O or Pr(NO3)(3).6H(2)O and pyridine-2,6-dicarboxylic acid form a linear coordination polymeric structure under hydrothermal conditions. Hexameric water clusters join these linear chains through bonding to the metal ions. Other coordinated water and the carboxylate oxygen form an intricate array of hydrogen bonding resulting in a 3D network where each metal ion shows 9-coordination with an approximate D-3 symmetry. Dimeric water clusters are also located in the void spaces. In the structure containing Pr(III), the water dimers are hydrogen-bonded to the hexamers, whereas in the Ce(III) structure, the dimers and the hexamers are far apart.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available