4.5 Article

One-pot synthesis of α-amino phosphonates using samarium diiodide as a catalyst precursor

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2003, Issue 24, Pages 4728-4730

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200300545

Keywords

samarium; iodine; synthetic methods; lanthanides

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A simple and efficient preparation of alpha-amino phosphonates under relatively mild conditions by the one-pot reaction of aldehydes with amines and dialkyl phosphites using catalytic amounts of SmI2 is described. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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