Journal
ORGANIC LETTERS
Volume 5, Issue 26, Pages 5035-5038Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol036071v
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- NIGMS NIH HHS [GM 42897] Funding Source: Medline
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[GRAPHICS] A convergent, second generation formal synthesis of (+)-Leucascandrolide A (1) has been efficiently achieved by providing a flexible, enantiocontrolled strategy toward the bioactive macrolactone component. Advancements for stereocontrol in asymmetric allylation methodology are discussed. Efforts feature novel results for reductions using the Terashima hydride reagent.
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