Journal
ORGANIC LETTERS
Volume 5, Issue 26, Pages 4935-4938Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0357191
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[GRAPHICS] Porphyrin macrocycles composed of five and six units of m-gable imidazolylporphyrinatozinc (1-Zn) were synthesized by self-assembled cyclization followed by ring-closing metathesis linkings. Each porphyrin macrocycle was isolated by GPC chromatography, and their molecular weights were determined by MALDI-TOF mass spectroscopy. These structures represent mimics of light-harvesting complexes in photosynthetic bacteria.
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