4.7 Article

Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 1, Pages 38-39

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b311268n

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A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

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