Journal
ADVANCED MATERIALS
Volume 16, Issue 2, Pages 180-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200305333
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Poly(3-perfluorooctylthiophene) is the first reported conjugated polymer that is soluble in supercritical carbon dioxide (see Figure). The electron-withdrawing nature of the perfluoroalkyl groups affords a material that undergoes reversible reduction (n-doping), and the polymer displays a large Stokes shift because of a large difference in the conformation of the ground state and a more planar excited state.
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