4.6 Article

Surface ordering of amphiphilic ionic liquids

Journal

LANGMUIR
Volume 20, Issue 2, Pages 309-312

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/la035495v

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Neutron reflectometry measurements suggest that the interfacial structure normal to the free surface of two short-chain amphiphilic 1-alkyl-3-methylimidazolium-based ionic liquids is inhomogeneous, with the inhomogeneity extending similar to40 Angstrom. For the two liquids studied (1-butyl-3-methylimidazolium tetrafluoroborate and 1-octyl-3-methylimidazolium hexafluorophosphate), the data are consistent with a stratified surface model with distinct regions of alkyl chains and ionic headgroups.

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