Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 2, Pages 244-245Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b313417m
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New efficient vanadium co-catalysts have been developed for the oxidation of some alcohols with O-2 catalysed by N-hydroxyphthalimide (NHPI). Various alcohols (primary and secondary) were selectively oxidized by O-2 under mild conditions in the presence of a catalytic amount of NHPI as a radical-producing agent combined with small amounts of vanadium complexes with or without the addition of a simple salt (e.g. LiCl) or base (e.g. pyridine).
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