4.5 Review

How to make ohmic contacts to organic semiconductors

Journal

CHEMPHYSCHEM
Volume 5, Issue 1, Pages 16-25

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.200300942

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The process of charge injection plays an important role in organic semiconductor devices. We review various experimental techniques that allow injection to be separated from other competing processes, and quantify the injection efficiency of a contact. We discuss the dependence of the injection efficiency on parameters such as the energy barrier at the interface, the carrier mobility of the organic semiconductor, its carrier density (doping level), the presence of mobile ions, and the sample geometry. Based on these findings, we outline guidelines for forming ohmic contacts and present examples of contact engineering in organic semiconductor devices.

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