Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 2, Pages 169-172Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2003.10.034
Keywords
barium titanate; citrate; precursor; pechini process; crystal structure
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Diammonium dibarium hydrogen citrato peroxotitanate(IV), Ba-2(NH4)(2)[Ti-4(O-2)(4)(Hcit)(2)(cit)(2)] . 10H(2)O, is obtained directly from H2O2 oxidation of tricitrato titanate, or from the reaction of peroxotitanate with citric acid (H(4)cit = citric acid), which is decomposed stoichiometrically into BaTi2O5 at the temperature of 800 degreesC in air. (C) 2003 Elsevier B.V. All rights reserved.
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