4.1 Article

Crystal structures and excimer fluorescence of anisoylbenzoylmethanatoboron and dianisoylmethanatoboron difluorides

Journal

RUSSIAN CHEMICAL BULLETIN
Volume 53, Issue 2, Pages 291-296

Publisher

SPRINGER
DOI: 10.1023/B:RUCB.0000030800.71663.7a

Keywords

fluorescence; crystal structure; X-ray diffraction analysis; excimer; beta-diketonatoboron difluorides

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The crystal structures and spectral-luminescence properties of anisoylbenzoylmethanatoboron difluoride (1) and dianisoylmethanatoboron difluoride (2) were studied in the solid state and in solution. The structural features of Compounds 1 and 2 are responsible for the Occurrence of a new type of excimers in Solutions, which differs from that observed in the crystalline state.

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