Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 2, Pages 274-276Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2003.11.020
Keywords
ruthenium(III) Schiff base complexes; characterization; redox properties; catalytic oxidation
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Twelve low spin ruthenium(III) Schiff base complexes of the type [RuX(EPh3) (LL')] (where X = Cl or Br; E = P or As; LL' = dibasic tetradentate Schiff base) were synthesized and characterized. These complexes catalyze oxidation of primary alcohol with up to 87.9% in the presence of N-methylmorpholine-N-oxide (NMO). (C) 2003 Elsevier B.V. All rights reserved.
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