4.7 Article

Octahedral hexanuclear silver(I) and copper(I) ferrocenylacetylide complexes

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 7, Issue 2, Pages 286-288

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2003.11.026

Keywords

copper(I); crystal structure; ethynylferrocene; silver(I)

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Octahedral hexanuclear ferrocenylacetylide complexes [Ag-6(mu-dppm)(2)(mu(3)-eta(1)-CdropCFc)(4)(CH3OH)(2)](BF4)(2) (1) and [CU6(mu-dppm)(2)(mu(3)-eta(1)-Cdrop-CFc)(4)(ClO4)(2)] (2) (dppm = Ph2PCH2PPh2, Fe = ferrocenyl) are synthesised and characterized structurally. (C) 2003 Elsevier B.V. All rights reserved.

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