4.3 Article

Synthesis of 2-aminochromene derivatives catalyzed by KF/Al2O3

Journal

SYNTHETIC COMMUNICATIONS
Volume 34, Issue 3, Pages 509-514

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1081/SCC-120027291

Keywords

2-aminochromene; naphtho[1,2-b;6,5-b ']dipyrans; synthesis

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A series of 2-aminochromene derivatives include 2-aminobenzo-[h]chromene and naphtha[1,2-b;6.5-b']dipyrans derivatives were synthesized from arylaidehyde, malononitrile or ethyl cyanoacetate, with 1-naphthol or 1,5-naphthalenediol in refluxing ethyl alcohol catalyzed by KF-Al2O3. The structure of the products was confirmed by X-ray analysis.

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